Abstract
The use of chloride in selectively forming high cis-1,4-polyisoprene in a comparison of equivalent binary and ternary lanthanide systems, was investigated. Gel permeation chromatography (GPC) was used for the analysis of these polymers and showed that these polymers had monomodal molecular weight distribution. The C NMR spectroscopy showed that the polymers which were generated in the binary system were a mixture of cis- and trans-1,4- polyisoprene. The results confirm the existence of significant chloride effect in a controlled system.
| Original language | American English |
|---|---|
| Pages (from-to) | 5130-5132 |
| Number of pages | 3 |
| Journal | Macromolecules |
| Volume | 37 |
| Issue number | 13 |
| DOIs | |
| State | Published - Jun 29 2004 |
| Externally published | Yes |
ASJC Scopus Subject Areas
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry
Disciplines
- Chemistry
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