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Sex‐specific mercury levels in skin samples of southern elephant seals (Mirounga leonina) at Isla 25 de Mayo (King George Island), Antarctic Peninsula

  • Dalia C. Barragán‐Barrera
  • , Federico G. Riet‐Sapriza
  • , Diego F. Mojica‐Moncada
  • , Javier Negrete
  • , Antonio Curtosi
  • , Paco Bustamante
  • , Susana Caballero
  • , Andrea Luna‐Acosta

Research output: Contribution to journalArticlepeer-review

Abstract

The southern elephant seal (SES; Mirounga leonina) has a circumpolar distribution, breeding mainly on sub-Antarctic islands and making long trips between breeding or molting and foraging areas. Most individuals from colonies in the South Shetland Islands (western Antarctic Peninsula; WAP) are distributed in Antarctic Specially Protected Areas (ASPA). Despite these protected habitats, pollutants can reach such remote areas far away from emission sources, affecting local fauna. To assess possible mercury (Hg) contamination in SES, we analyzed skin samples collected from free-ranging molting individuals using the remote biopsy PAXARMS system in Isla 25 de Mayo/King George Island (62°15′S, 58°39′W; ASPA 132). Hairless skin samples were analyzed to determine total-Hg (THg) concentrations, which ranged between 145 ng/g and 1,915 ng/g (M = 730, SD = 388 ng/g), showing significant differences between sexes, with adult-females having higher concentrations (range = 306–1,915, M = 859, SD = 427 ng/g dw) than subadult-males (range = 145–1,645, M = 629, SD = 329 ng/g dw). These differences may be explained mainly by feeding-niche partitioning between sexes. Females prefer mesopelagic prey or prey associated with sea-ice in the WAP, which are enriched in methylmercury. These results provide insight regarding Hg contamination in top Antarctic predators like SES, and the need to monitor for potential effects of Hg contamination in Antarctic marine mammals.
Original languageUndefined/Unknown
Pages (from-to)108-122
Number of pages15
JournalMarine Mammal Science
Volume40
Issue number1
DOIs
StatePublished - Jul 30 2023
Externally publishedYes

Funding

We are grateful to M. Brault-Favrou and C. Churlaud from the Platefome Analyses Elémentaires of LIENSs as well as N. Vélez for their assistance in mercury analyses. We are also grateful for the logistical support from the Comisión Colombiana del Océano (Coordinator of the Colombian Antarctic Program), the Armada Nacional de Colombia, the “ARC 20 de Julio” crew, the Dirección Nacional del Antártico-DNA (Dr. Mariano Memolli), the Argentine Antarctic Institute (Dr. Néstor Coria), and the marine mammal field staff of the Argentine Antarctic Base Carlini who assisted in the collecting of the samples. Special thanks to C. Bermúdez for his support making the violin plot. Thanks are due to the CPER (Contrat de Projet Etat-Région) and the FEDER (Fonds Européen de Développement Régional) for funding the ICPs, the AMA, and the IRMS of LIENSs laboratory. The IUF (Institut Universitaire de France) is acknowledged for its support to P.B. as a Senior Member, as well as the Colombian Sciences Ministry for granting a Postdoctoral Fellowship to D.B. through the Francisco José de Caldas Fund (Call No 848 of 2019). The Vicerrectoría de Investigaciones from Pontificia Universidad Javeriana is also acknowledged for providing a Postdoctoral Grant (Call 2021-2) to D.B. (2022), who also thanks the Instituto Javeriano del Agua for its support during the Postdoctoral tenure. We also thank the anonymous reviewers whose comments improved the final version of this manuscript. This research was funded by the Argentine Antarctic Institute (Picta 2010-01) to J.N, the Comisión Colombiana del Océano to D.M., the Universidad de Los Andes to F.R., and the Scientific Committee of Antarctic Research – SCAR to D.B. [Correction added on August 8, 2023, after first online publication: The following sentence has been modified “This research was funded by the Argentine Antarctic Institute…” to clarify funding.] Sampling methodology was approved by the Environmental Office of the Dirección Nacional del Antártico (Argentina) as well as the Dirección General Marítima (Colombia), following the Protocol on Environmental Protection to the Antarctic Treaty guidelines. Based on this approval, the Dirección Nacional del Antártico-Argentinian Antarctic Institute and the Colombian Antarctic Program provided the collection permits (Reference number 7 and No. 29201600004 MD-DIMAR-SUBDEMAR, respectively). The methodology for sample collection was approved by the Ethical Committee from Universidad de Los Andes (ID PR.6.2016.3551).

Funders
Universidad de Los Andes, Colombia
Instituto Antártico Argentino
Scientific Committee on Antarctic Research
Society for Marine Mammalogy

    Keywords

    • Antarctica
    • contamination
    • elephant seal
    • heavy metals
    • Hg
    • mercury
    • pinnipeds
    • South Shetland Islands

    Disciplines

    • Marine Biology

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