The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n

William J. Evans; Jason C. Brady; Cy H. Fujimoto; Dimitrios G. Giarikos; Joseph W. Ziller

doi:10.1016/s0022-328x(02)01138-5

The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n

William J. Evans
, Jason C. Brady
, Cy H. Fujimoto
, Dimitrios G. Giarikos
, Joseph W. Ziller

Research output: Contribution to journal › Article › peer-review

Abstract

THF-solvated KC5Me5 and KC5Me4SiMe2CH2CHCH2 complexes crystallize with extended structures that provide information on bent metallocenes containing potassium, [(μ-C5R5)K(μ-C5R5)]−. The substructures of [(THF)K(μ-C5Me5)]n, [(THF)2K(μ-C5Me5)]n, and [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n display (μ-C5R5)K(μ-C5R5) angles of 137.9–143.7°. The olefin substituent in [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n approaches potassium with K⋯C distances of 3.58 and 4.20 Å.
The polymeric solid state structures of the title compounds generate [(μ-C5R5)K(μ-C5R5)]− substructures which have bent metallocene geometries as shown. A monosolvate, a disolvate and a monosolvate with a nearby olefin are reported.

Original language	English
Pages (from-to)	252-257
Journal	Journal of Organometallic Chemistry
Volume	649
Issue number	2
DOIs	https://doi.org/10.1016/s0022-328x(02)01138-5
State	Published - Apr 2002
Externally published	Yes

Funding

For support of this research, we thank the Division of Chemical Sciences of the Office of Basic Energy Sciences of the Department of Energy.

Keywords

Potassium
Cyclopentadienide
Bent metallocenes
Tethered olefins

Access to Document

10.1016/s0022-328x(02)01138-5

Fingerprint

Dive into the research topics of 'The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n'. Together they form a unique fingerprint.

Cite this

Evans, W. J., Brady, J. C., Fujimoto, C. H., Giarikos, D. G., & Ziller, J. W. (2002). The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n. Journal of Organometallic Chemistry, 649(2), 252-257. https://doi.org/10.1016/s0022-328x(02)01138-5

The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n. / Evans, William J.; Brady, Jason C.; Fujimoto, Cy H. et al.
In: Journal of Organometallic Chemistry, Vol. 649, No. 2, 04.2002, p. 252-257.

Research output: Contribution to journal › Article › peer-review

Evans, WJ, Brady, JC, Fujimoto, CH, Giarikos, DG & Ziller, JW 2002, 'The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n', Journal of Organometallic Chemistry, vol. 649, no. 2, pp. 252-257. https://doi.org/10.1016/s0022-328x(02)01138-5

Evans WJ, Brady JC, Fujimoto CH, Giarikos DG, Ziller JW. The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n. Journal of Organometallic Chemistry. 2002 Apr;649(2):252-257. doi: 10.1016/s0022-328x(02)01138-5

@article{411e456f17b244baa69def1be91aa8b2,

title = "The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n",

abstract = "THF-solvated KC5Me5 and KC5Me4SiMe2CH2CHCH2 complexes crystallize with extended structures that provide information on bent metallocenes containing potassium, [(μ-C5R5)K(μ-C5R5)]−. The substructures of [(THF)K(μ-C5Me5)]n, [(THF)2K(μ-C5Me5)]n, and [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n display (μ-C5R5)K(μ-C5R5) angles of 137.9–143.7°. The olefin substituent in [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n approaches potassium with K⋯C distances of 3.58 and 4.20 {\AA}. The polymeric solid state structures of the title compounds generate [(μ-C5R5)K(μ-C5R5)]− substructures which have bent metallocene geometries as shown. A monosolvate, a disolvate and a monosolvate with a nearby olefin are reported. ",

keywords = "Potassium, Cyclopentadienide, Bent metallocenes, Tethered olefins",

author = "Evans, \{William J.\} and Brady, \{Jason C.\} and Fujimoto, \{Cy H.\} and Giarikos, \{Dimitrios G.\} and Ziller, \{Joseph W.\}",

year = "2002",

month = apr,

doi = "10.1016/s0022-328x(02)01138-5",

language = "English",

volume = "649",

pages = "252--257",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "2",

}

TY - JOUR

T1 - The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)]n and the tethered olefin complex [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n

AU - Evans, William J.

AU - Brady, Jason C.

AU - Fujimoto, Cy H.

AU - Giarikos, Dimitrios G.

AU - Ziller, Joseph W.

PY - 2002/4

Y1 - 2002/4

N2 - THF-solvated KC5Me5 and KC5Me4SiMe2CH2CHCH2 complexes crystallize with extended structures that provide information on bent metallocenes containing potassium, [(μ-C5R5)K(μ-C5R5)]−. The substructures of [(THF)K(μ-C5Me5)]n, [(THF)2K(μ-C5Me5)]n, and [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n display (μ-C5R5)K(μ-C5R5) angles of 137.9–143.7°. The olefin substituent in [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n approaches potassium with K⋯C distances of 3.58 and 4.20 Å. The polymeric solid state structures of the title compounds generate [(μ-C5R5)K(μ-C5R5)]− substructures which have bent metallocene geometries as shown. A monosolvate, a disolvate and a monosolvate with a nearby olefin are reported.

AB - THF-solvated KC5Me5 and KC5Me4SiMe2CH2CHCH2 complexes crystallize with extended structures that provide information on bent metallocenes containing potassium, [(μ-C5R5)K(μ-C5R5)]−. The substructures of [(THF)K(μ-C5Me5)]n, [(THF)2K(μ-C5Me5)]n, and [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n display (μ-C5R5)K(μ-C5R5) angles of 137.9–143.7°. The olefin substituent in [(THF)K(μ-C5Me4SiMe2CH2CHCH2)]n approaches potassium with K⋯C distances of 3.58 and 4.20 Å. The polymeric solid state structures of the title compounds generate [(μ-C5R5)K(μ-C5R5)]− substructures which have bent metallocene geometries as shown. A monosolvate, a disolvate and a monosolvate with a nearby olefin are reported.

KW - Potassium

KW - Cyclopentadienide

KW - Bent metallocenes

KW - Tethered olefins

U2 - 10.1016/s0022-328x(02)01138-5

DO - 10.1016/s0022-328x(02)01138-5

M3 - Article

SN - 0022-328X

VL - 649

SP - 252

EP - 257

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 2

ER -